POLi Payments Pty Ltd (formerly known as Centricom) is an online payments company based in Melbourne, Australia. It is the developer and provider of POLi, Previous versions · Concerns · References. POLi is Australia's leading real-time online debit payment method. It offers a secure alternative to PayPal, BPAY and credit cards by giving customers the option. POLi allows consumers to make an online payment for goods and service, or pay a bill online using the security and convenience of Internet Banking.